Chili red pigment
Red pepper contains chili red pigment and capsaicin.
Capsaicin can be made into anti-tumor and analgesic drugs, and it is very popular in the international market.
Chili red pigment belongs to carotenoid pigments, including capsanthin, capsorubin, zeaxanthin, beta carotene, etc.
Capsanthin has bright colors and various tones. It is soluble in edible ethanol at 1:15. It is red at 1/5000, orange at 1/8000, and yellow at 1/12000. It is currently one of the most widely used natural pigments. , It is widely used in food, medicine, cosmetics, daily necessities and other fields.
Capsanthin does not have any side effects on the human body, so ADl (human daily intake) is stipulated internationally as “unrestricted”, and it has been produced in the world for a long time.
Currently the United States, Britain, Canada, Japan and other countries are in a leading position. Japan’s annual output is 260t, accounting for 1.1% of its domestic natural pigment market demand.
Capsaicin extraction method
Traditional extraction method
The traditional Capsanthin extraction methods are oil-soluble method and solvent method. The general process uses a two-step method:
Step 1: Extraction
First use an organic solvent to extract the plants to obtain a paste-like viscous liquid (commonly known as extract or oleoresin);
Step 2: Refining
Using organic reagents to extract, the soluble components in the plant are dissolved. In addition to useful pigments and fragrance components, there are also various impurities, especially tar smell, spicy smell and other peculiar smells.
- Refining is to remove the peculiar smell from the extract or oleoresin, that is, deodorization.
- The traditional refining method uses strong alkalis, strong acids and salts for washing. This method has a long process, high cost, and is easy to bring in heavy metal ions. Strong alkalis can also damage some pigments and affect the color tone.
- Later, there were many ways to improve, but in general, there were problems such as complex process, low product purity, peculiar smell, and high solvent residue.
Supercritical CO2 extraction method
At present, the research work using supercritical CO2 fluid to extract Chili red pigment and capsaicin mainly includes the direct extraction of capsanthin and capsaicin and the refining of capsicum oleoresin.
Experiments show that the optimal extraction conditions are particle size <1.2 mm, extraction pressure 15 MPa, and extraction temperature 50 ℃.
In the extraction process, the separation effect of capsicum pigment and capsaicin was judged according to the absorbance curve of 200-600 nm measured by UV3000 ultraviolet-visible spectrophotometer. The quality indicators of capsicum pigment extracted by this method exceeded China’s national standards.
Supercritical CO2 Fractional Distillation Extraction
Therefore, after supercritical fluid extraction of chili red pigments, supercritical CO2 fractionation technology is used for deodorization while improving the hot removal technology, which is conducive to the wider application of supercritical CO2 fluid extraction of pepper pigments.
The use of supercritical CO2 fluid extraction technology can greatly improve the quality of pepper pigment products. The product color price is high, the residual amount of organic solvents is small, and there is no thermal processing link to ensure that the original components in natural substances are not destroyed. It can be achieved near room temperature. The supercritical CO2 technology operation saves energy consumption and can remove the peculiar smell in pepper products.